化学学院
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基本信息



     

 

 

 

肖福红

 

 

职称:教授

性别:男

 

 

职务:教研室主任

办公电话:

 

 

移动电话:隐藏

家庭电话:

 

 

家庭住址:

电子邮箱:fhxiao@xtu.edu.cn

 

 

 

 

 

 

工作学习经历



 

2005.09-2009.06    东华理工大学 化学专业

本科 

2009.09-2014.06    湘潭大学化学学院 有机化学专业  

硕博连读 

2014.07-2016.12    湘潭大学化学学院 

讲师

2017.01-2023.12    湘潭大学化学学院

副教授

2024.01-至今         湘潭大学化学学院

教授

 

 

主讲课程



《有机化学》、《有机化学实验》、《高等有机化学》、《化学导论》

 

研究方向 



有机合成化学、非均相金属催化

 

主要学术成果 



围绕着绿色化学导向的有机合成反应这一核心主题,分别在廉价金属催化的反应和氧气为氧化剂的绿色氧化反应开展了系统的研究工作。参加工作以来,申请人共发表包括Green ChemistryOrganic LettersAdvanced Synthesis & Catalysis SCI 论文 40余篇,先后有篇论文入选ESI高被引论文,论文他引次数超过1000次,授权中国发明专利6项。同时绿色化学导向的醇和酮脱氢转化反应研究的研究成果获2015 年湖南省自然科学二等奖(排名第2),2016 年获湖南省优秀博士学位论文。

 

 

 

 

【科研论文】

49Enbo Yu, Guojiang Mao, Guo-Jun Deng *, Fuhong Xiao*, Transition-metal-free chemoselective reduction of

α,β-unsaturated ketones using H2O as a hydrogen source, Org. Chem. Front., 2023, 10, 4703–4708.

48Yanfeng Ma, Tianci Xu, Fuhong Xiao,* Guojiang Mao, Guo-Jun Deng*, Modular synthesis of unsymmetric 2,4-diarylsubstituted pyridines through a four-component cyclization strategy under metal-free conditions, Org. Chem. Front., 2023, 10, 4794–4799.

47Fuhong Xiao,* Enbo Yu, Ya Chen, Guo-Jun Deng*, Three-Component Synthesis of Thiazole-2-thione from Chalcone, Nitrobenzene and Carbon Disulfide, Adv. Synth. Catal. 2023, 365, 4150– 4154.

46Lin Yao, Wenjian Li, Fuhong Xiao,* and Guo-Jun Deng*, Three-Component Tandem Amidosulfenylation of Alkenes for the Synthesis of β‑Succinimide Sulfides, J. Org. Chem. 2023, 88, 13956−13966.

45Yufeng Chen, Ruitong Yang, Fuhong Xiao*, Tianci Xu, Guojiang Mao, and Guo-Jun Deng*, Copper-Catalyzed Synthesis of 3‑Aryl‑9H‑imidazo[1,5‑a]indol-9-ones Using Oxygen as the Sole Oxidant, Org. Lett. 2023, 25, 3702−3707.

44Yufeng Chen, Ruitong Yang, Fuhong Xiao*, Tong Li, Guojiang Mao, Guo-Jun Deng*, Four-Component Synthesis of 9H-Pyrimido[4,5-b]indoles Using Ammonium Iodide as the Nitrogen Source, Catalysts, 2023, 13, 623-647.

43Yanfeng Ma, Chunlan Zhou, Fuhong Xiao*, Guojiang Mao, and Guo-Jun Deng*, Three-Component Synthesis of 2‑Substituted Quinolines and Benzo[f ]quinolines Using Tertiary Amines as the Vinyl Source, J. Org. Chem. 2023, 88, 2952-2960.

42Quanyuan Wang, Fuhong Xiao*, Zhi Huang, Guojiang Mao, Guo-Jun Deng*, CuBr2‑Catalyzed Annulation of 2‑Bromo‑N‑Arylbenzimidamide with Se/S8 Powder for the Synthesis of Benzo[d]isoselenazole and Benzo[d]isothiazole, J. Org. Chem. 2023, 88, 1963-1976.

41Jiaxing Chen, Yongzhuo Xu, Wen Shao*, Jianhua Ji, Boqiang Wang, Muyang Yang, Guojiang Mao, Fuhong Xiao*, Guo-Jun Deng*, Pd-Catalyzed C−O Bond Formation Enabling the Synthesis of Congested N,N,O‑Trisubstituted Hydroxylamines, Org. Lett. 2022, 24, 8271-8276.

40Gang Yang, Lin Yao, Guojiang Mao, Guo-Jun Deng, Fuhong Xiao*, Synthesis of Indenoquinolinones and 2Substituted Quinolines via [4 + 2] Cycloaddition Reaction, J. Org. Chem. 2022, 87, 14523-14535.

39Fuhong Xiao*, Gang Yang, Lin Yao, Guojiang Mao, Guo-Jun Deng*, Fe-Catalyzed Three-Component Reaction for the Synthesis of 2,3’-Biquinolines, Adv. Synth. Catal. 2022, 364, 3501-3505.

38Dahan Wang, Li Zhang, Fuhong Xiao*, Guojiang Mao, Guo-Jun Deng*, The Electrochemically Selective C3-Thiolation of Quinolines, Org. Chem. Front., 2022, 9, 2986-2993.

37Minli Tang, Li Zhang, Guojiang Mao, Fuhong Xiao*, Wen Shao, and Guo-Jun Deng*, Direct Thioamination of Cyclohexanones via Difunctionalization with Thiophenol and Aniline, Adv. Synth. Catal. 2022, 364, 2205-2210.

36Qiaoyan Xing, Fuhong Xiao*, Guojiang Mao, Guo-Jun Deng*, A Four-Component Reaction for the Synthesis of Thienopyrrolediones under Transition Metal Free Conditions, Org. Lett. 2022, 24, 4377-4382.

35Fuhong Xiao*, Minli Tang, Huawen Huang, Guo-Jun Deng, Site-Selective Synthesis of Aryl Sulfides via Oxidative Aromatization of Cyclohexanones with Thiophenols, J. Org. Chem. 2022, 87, 512-523.

34Yanfeng Ma, Shanghui Wu, Shuxin Jiang, Fuhong Xiao*, Guo-Jun Deng*, Electrosynthesis of Azobenzenes Directly from Nitrobenzenes, Chin. J. Chem. 2021, 39, 3334-3338.

33Li Liu, Hong Xiao, Fuhong Xiao*, Yanjun Xie, Huawen Huang*, Guojun Deng, Synthesis of β-Ketosulfone from Sodium Sulfinate and Aryl Ethyl Ketone/Indanone, Chin. J. Org. Chem. 2021, 41, 4749-4757.

32Dahan Wang, Fuhong Xiao*, Feng Zhang, Guo-Jun Deng*, Three-Component Synthesis of 2-Heteroaryl-3-hydroxybenzo[b]thiophenes under Transition-Metal-Free Conditions, Chin. J. Chem. 2021, 39, 2483-2488.

31Dahan Wang, Fuhong Xiao*, Feng Zhang, Huawen Huang, Guo-Jun Deng*, Copper-Catalyzed Aerobic OxidativeRing Expansionof Isatins: A Facile Entry to Isoquinolino-Fused Quinazolinones, Chin. J. Chem. 2021, 39, 87-92.

30Fuhong Xiao*, Yangling Hu, Huawen Huang, Fen Xu*, Guo-Jun Deng, Base-Controlled Divergent Synthesis of Vinyl Sulfones from (Benzylsulfonyl)benzenes and Paraformaldehyde, Org. Biomol. Chem., 2020, 18, 3527-3535.

29Jinjin Chen, Dan Chang, Fuhong Xiao*, Guo-Jun Deng*, Three-Component Ordered Annulation of Amines, Ketones, and Nitrovinylarenes: Access to Fused Pyrroles and Substituted Indoles under Metal-Free Conditions, J. Org. Chem. 2019, 84, 568-578.

28Fuhong Xiao*, Shanshan Yuan, Huawen Huang*, Feng Zhang, Guo-Jun Deng, Copper-Catalyzed Three-Component Domino Cyclization for the Synthesis of 4‑Aryl-5-(arythio)-2-(trifluoromethyl)oxazolesOrg. Lett. 2019, 21, 8533-8536.

27Dahan Wang, Feng Zhang, Fuhong Xiao*, Guo-Jun Deng*, A Three-Component Approach to Isoxazolines and Isoxazoles under Metal-Free Conditions, Org. Biomol. Chem., 2019, 17, 9163-9168.

26Jingxin Tian, Shanshan Yuan, Fuhong Xiao*, Huawen Huang, Guo-Jun Deng*, Concise Synthesis of N-Thiomethyl Benzoimidazoles Through Base-Promoted Sequential Multicomponent Assembly, RSC Adv., 2019, 9, 30570-30574.

25Fuhong Xiao*, Shanshan Yuan, Dahan Wang, Saiwen Liu,* Huawen Huang, and Guo-Jun Deng, Thioesters as Bifunctional Reagents for 2-Naphthylamine Sulfuracylation, Adv. Synth. Catal., 2019361, 3331-3336.

24Hao Xie, Qiaoyan Xing, Zhifei Shan, Fuhong Xiao*, Guo-Jun Deng*, Nickel-Catalyzed Annulation of o-Haloarylamidines with Aryl Acetylenes: Synthesis of Isoquinolone and 1-Aminoisoquinoline Derivatives, Adv. Synth. Catal., 2019361, 1896-1901.

23Penghui Ni, Jing Tan, Wenqi Zhao, Huawen Huang, Fuhong Xiao*, Guo-Jun Deng*, Metal-Free Double Csp2H Bond Functionalization: Strategy for Synthesizing Benzo[a]carbazoles from 2Arylindoles and Acetophenones/Alkynes, Org. Lett., 201921, 3687-3691.

22Penghui Ni, Jing Tan, Wenqi Zhao, Huawen Huang, Fuhong Xiao*, Guo-Jun Deng*, A Three-Component Strategy for Benzoselenophene Synthesis under Metal-Free Conditions Using Selenium Powder, Org. Lett., 201921, 3518-3522.

21Fuhong Xiao*, Shanshan Yuan, Huawen Huang, Guo-Jun Deng*, Base-Promoted Three-Component One-Pot Synthesis of 3-(Thiomethyl)indoles with Paraformaldehyde under Aqueous Conditions, Synlett201829, 2693-2696.

20Fuhong Xiao*, Dahan Wang, Shanshan Yuan, Huawen Huang, Guo-Jun Deng, Iodine-Promoted Stereoselective Amidosulfenylation of Electron-deficient Alkynes, RSC Adv.20188, 23319-23322.

19Fuhong Xiao*, Chao Liu, Shanshan Yuan, Huawen Huang, Guo-Jun Deng*, A Four-Component Reaction for the Synthesis of βQuinoline Allylic Sulfones under Iron Catalysis, J. Org. Chem.201883, 10420-10429.

18Fuhong Xiao*, Chao Liu, Dahan Wang, Huawen Huang, Guo-Jun Deng*, Concise Synthesis of Ketoallyl Sulfones Through an Iron-Catalyzed Sequential Four-Component Assembly, Green Chem., 201820, 973-977.

17Jinjin Chen, Dan Chang, Fuhong Xiao*, Guo-Jun Deng*, Four-Component Quinazoline Synthesis from Simple Anilines, Aromatic Aldehydes and Ammonium Iodide under Metal-Free Conditions, Green Chem.201820, 5459-5463.

16Penghui Ni, Bin Li, Huawen Huang, Fuhong Xiao*, Guo-Jun Deng*, Solvent-Controlled Highly Regioselective Thieno[2,3-b]indole Formation under Metal-Free Conditions, Green Chem., 201719, 5553-5558.

15Bin Li, Penghui Ni, Huawen Huang, Fuhong Xiao*, Guo-Jun Deng,* Three-Component Thieno[2,3-b]indole Synthesis from Indoles, Alkenes or Alkynes and Sulfur Powder under Metal-Free Conditions, Adv. Synth. Catal.2017359, 4300-4304.

14Xiangui Chen, YanjunXie, Cheng Li, Fuhong Xiao*, Guo-Jun Deng*, Synthesis of Substituted Acridines through a Palladium-Catalyzed Condensation/Cyclization/Tautomerization Sequence, Eur. J. Org. Chem. 2017, 577-581.

13Fuhong Xiao*, Jingxin Tian, Qiaoyan Xing, Huawen Huang, Guo-Jun Deng, Yuejin Liu*, Piperidine Promoted Direct Sulfenylation of 2-Naphthol with Aryl Thiols under Aqueous Conditions, ChemistrySelect 20172, 428-431.

12Xiufang Cheng, Huamin Wang, Fuhong Xiao*, Guo-Jun Deng*, Lewis Acid-catalyzed 2-Arylquinazoline Formation from N'-Arylbenzimidamides and Paraformaldehyde, Green Chem., 2016, 18, 5773-5776.

11Fuhong Xiao*, Shuqing Chen, Cheng Li,  Huawen Huang and Guo-Jun Deng*, Cu-Catalyzed Three-Component One-Pot Synthesis of Aryl Sulfide with Sulfur Powder under Aqueous Conditions. Adv. Synth. Catal., 2016, 358, 3881-3886.

10Fuhong Xiao*, Shuqing Chen, Jingxin Tian, Huawen Huang, Yuejin Liu*, Guo-Jun Deng*, Chemoselective Cross-Coupling Reaction of Sodium Sulfinates with Phenols under Aqueous Conditions, Green Chem., 2016, 18, 1538-1546

9Jinjin Chen, Guozheng Li, Yanjun Xie, Yunfeng Liao, Fuhong Xiao*, Guo-Jun Deng*, Four-Component Approach to N-Substituted Phenothiazines under Transition-Metal-Free Conditions, Org. Lett., 2015, 17, 5870-5873.

8Fuhong Xiao*, Shuqing Chen, Huawen Huang, Guo-Jun Deng, Palladium-Catalyzed Oxidative Direct ortho -C-H Acylation of Arenes with Aldehydes under Aqueous Conditions, Eur. J. Org. Chem. 2015, 7919-7925.

7Fuhong Xiao*, Shuqing Chen, Ya Chen, Huawen Huang, Guo-Jun Deng*, Efficient 2-Sulfolmethyl Quinoline Formation from 2-Methylquinolines and Sodium Sulfinates under Transition-metal free Conditions. Chem. Commun. 2015, 51, 652-654.

6Fuhong Xiao, Hui Chen, Hao Xie, Shuqing Chen, Luo Yang, Guo-Jun Deng*, Iodine-Catalyzed Regioselective 2- Sulfonylation of Indoles with Sodium Sulfinates, Org. Lett. 2014, 16, 50-53.

5Fuhong Xiao, Hao Xie, Saiwen Liu, Guo-Jun Deng*, Iodine-Catalyzed Regioselective Sulfenylation of Indoles with Sodium Sulfinates, Adv. Synth. Catal. 2014, 356, 364-368.

4Fuhong Xiao, Wen Chen, Yunfeng Liao, Guo-Jun Deng*, Cu(II) Promoted Three-Component Coupling Sequence for the Efficient Synthesis of Substituted Quinolines, Org. Biomol. Chem. 2012, 10, 8593-8596.

3Fuhong Xiao, Yunfeng Liao, Mingyue Wu, Guo-Jun Deng*, One-Pot Synthesis of Carbazoles from Cyclohexanones and Arylhydrazine Hydrochlorides under Metal-Free Conditions, Green Chem. 2012, 14, 3277-3280.

2Fuhong Xiao, Yong Liu, Chenglin Tang, Guo-Jun Deng*, Peroxide Mediated Transition Metal Free Direct Amidation of Alcohols with Nitroarenes, Org. Lett. 2012, 14, 984-987.

1Fuhong Xiao, Qi Shuai, Feng Zhao, Olivier Basle, Guo-Jun Deng*, Chao-Jun Li*, Palladium-Catalyzed Oxidative sp2 C-H Bond Acylationwith Alcohols. Org. Lett. 201113, 1614-1617.

【授权专利】

1肖福红,田晶鑫,邓国军,黄华文,“一种化合物及其盐及其合成方法”,中国发明专利,ZL 201710227629.3

2肖福红,刘超,邓国军,黄华文,1-苯基-2-(苯基砜)甲基-2-丙烯-1-酮、衍生物及其合成方法”, ZL 201711325274.8

3肖福红,袁珊珊,邓国军,黄华文,1-甲基硫苯基苯并咪唑及其衍生物合成方法”, ZL 201810396470.2

4肖福红,袁珊珊,邓国军,黄华文,3-(甲硫基)-2-苯基苯并[b]噻吩衍生物及其合成方法”, ZL 201810396466.6

【科研项目】

1、钴基金属氧化物催化非张力环状碳碳键断裂的反应研究,湖南省教育厅重点项目(23A0103),主持,在研。

2基于相邻C(sp3)-H键为乙烯基源的芳烃选择性构筑,国家自然科学基金面上项目(22271244)参与2023-2026年,在研。

3以亚磺酸盐为硫源的高选择性C-S键生成反应研究,国家自然科学基金青年项目(21502160),主持,已结题。

4、以亚磺酸盐为硫源的高选择性C-S键生成反应研究,第57批中国博士后科学基金面上二等资助(2015M572257),主持 ,已结题。

5、亚磺酸盐与杂环C-H键的高选择性C-S键生成反应研究,湖南省自科基金青年项目(2016JJ3112主持 ,已结题。

6电化学促进的硝基还原及功能化反应研究,湖南省教育厅优秀青年项目(19B564),主持,已结题。

7、以亚磺酸盐为硫源的高选择性C-S键生成反应研究,湖南省教育厅一般项目(15C1311),主持,已结题。

【荣誉奖励】

10十三届湖南省大学生化学化工学科竞赛(创新作品)三等奖,指导老师,2023

9十三届湖南省大学生化学化工学科竞赛(化学实验技能)二等奖,指导老师,2023

8、第十二届湖南省大学生化学化工学科竞赛(化学实验技能)一等奖,指导老师,2022

7、第八届湖南省大学生化学化工实验与创新设计竞赛一等奖指导老师 2018

6、第八届湖南省大学生课外化学化工创新作品竞赛三等奖指导老师 2016

5、第六届湖南省大学生化学实验技能竞赛一等奖指导老师2016

4、第五届湖南省大学生化学实验技能竞赛二等奖指导老师2015

3、湖南省自然科学奖二等奖排名第二 2015

2、湖南省优秀博士论文2015

1、湘潭市自然科学优秀学术论文一等奖  2015

 

个人简介 



肖福红,男,汉族,中共党员,江西赣州人。2009年进入湘潭大学化学学院有机化学专业硕博连读,师从邓国军教授。2014年,博士毕业后留校任教,加入湘潭大学邓国军课题组,主要从事于有机合成方法学和非均相催化研究。主持国家自然科学基金青年项目和湖南省自然科学基金青年项目等项目,作为主要研究人员参与了国家自然科学基金面上项目和教育部新世纪人才计划等重大研究项目。到目前为止,以第一作者或通讯作者在Org. LettOrg. Chem. Front.Adv. Synth. Catal.J. Org. ChemChin. J. ChemGreen Synth. Catal等国内外核心期刊上发表SCI论文40篇。

 

绿色有机合成与催化研究团队每年可招收多名有机化学方向的硕士研究生和博士研究生,欢迎有志于有机合成化学研究的优秀学生报考。

 

团队负责人:邓国军教授;主页:https://bwcx.xtu.edu.cn/hxxy/info/1059/4467.htm

 

 

        

 

  
 

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